Daughter of musicians Dorival Caymmi and Stella Maris, and sibling of Danilo and Dori Caymmi, Nana was raised in one of the most musical families in Brazil. Nana started singing at an early age and adopted a singular technique which enhanced her low pitch voice. In 1961 she recorded her father's song "Acalanto", and then moved with her husband to Venezuela, an withdrawing from the music bizz for that period.

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